BRIDGED HEMILABILE ALLYLPHOSPHONATE LIGAND - SYNTHESIS AND CRYSTAL-STRUCTURE OF A NEW BINUCLEAR RHODIUM COMPLEX

Authors
LEGALL I LAURENT P TOUPET L SALAUN JY DESABBAYES H
Citation
I. Legall et al., BRIDGED HEMILABILE ALLYLPHOSPHONATE LIGAND - SYNTHESIS AND CRYSTAL-STRUCTURE OF A NEW BINUCLEAR RHODIUM COMPLEX, Organometallics, 16(16), 1997, pp. 3579-3581
Citations number
28
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Organometallics → ACNP
ISSN journal
02767333
Volume
16
Issue
16
Year of publication
1997
Pages
3579 - 3581
Database
ISI
SICI code
0276-7333(1997)16:16<3579:BHAL-S>2.0.ZU;2-I
Abstract
The reaction of 2 equiv of the allylphosphonate CH2=CH-CH2-P(O)(OEt)(2 ) with [Rh(Cl)(CO)(2)](2) results in the formation of a new binuclear rhodium complex with two bridged bidentate allylphosphonate ligands in cis positions, reaction with carbon monoxide induces the lability of the phosphonate moiety, which is reversible.