The tetramethylpiperidinyl-1-oxide anion (TMPO-) as a ligand in lanthanidechemistry: synthesis of the per( TMPO-) complex [(ONC5H6Me4)(2)Sm(mu-ONC5H6Me4)](2)

Authors
Evans, WJ Perotti, JM Doedens, RJ Ziller, JW
Citation
Wj. Evans et al., The tetramethylpiperidinyl-1-oxide anion (TMPO-) as a ligand in lanthanidechemistry: synthesis of the per( TMPO-) complex [(ONC5H6Me4)(2)Sm(mu-ONC5H6Me4)](2), CHEM COMMUN, (22), 2001, pp. 2326-2327
Citations number
12
Categorie Soggetti
Chemistry
Journal title
CHEMICAL COMMUNICATIONS
ISSN journal
13597345 → ACNP
Issue
22
Year of publication
2001
Pages
2326 - 2327
Database
ISI
SICI code
1359-7345(2001):22<2326:TTA(AA>2.0.ZU;2-5
Abstract
(C5Me5)(3)Sm reacts with the free radical 2,2,6,6-tetramethylpiperidinyl-1- oxy (TMPO) to form (C5Me5)(2) and the per nitroxide [(eta (1)-ONC5H6Me4)(2) Sm(mu-eta (1) : eta (2)-ON-C5H6Me4)](2).