Manganese as a template: a new synthesis of corrole

Authors
Broring, M Hell, C
Citation
M. Broring et C. Hell, Manganese as a template: a new synthesis of corrole, CHEM COMMUN, (22), 2001, pp. 2336-2337
Citations number
31
Categorie Soggetti
Chemistry
Journal title
CHEMICAL COMMUNICATIONS
ISSN journal
13597345 → ACNP
Issue
22
Year of publication
2001
Pages
2336 - 2337
Database
ISI
SICI code
1359-7345(2001):22<2336:MAATAN>2.0.ZU;2-B
Abstract
The reaction of 2,2'-bisdipyrrins 1, 2, and 3 with manganese( II) acetate t etrahydrate and molecular dioxygen yields the manganese(III)corroles 4, 5 a nd 6, which are readily demetalated to the respective free-base corroles.