Ruthenium-catalysed asymmetric hydrosilylation of ketoximes using chiral oxazolinylferrocenylphosphines

Authors
Takei, I Nishibayashi, Y Ishii, Y Mizobe, Y Uemura, S Hidai, M
Citation
I. Takei et al., Ruthenium-catalysed asymmetric hydrosilylation of ketoximes using chiral oxazolinylferrocenylphosphines, CHEM COMMUN, (22), 2001, pp. 2360-2361
Citations number
30
Categorie Soggetti
Chemistry
Journal title
CHEMICAL COMMUNICATIONS
ISSN journal
13597345 → ACNP
Issue
22
Year of publication
2001
Pages
2360 - 2361
Database
ISI
SICI code
1359-7345(2001):22<2360:RAHOKU>2.0.ZU;2-H
Abstract
Chiral ruthenium(II) complexes, RuCl2(PPh3)(oxazolinylferrocenylphosphine), have been found to be effective catalysts for asymmetric hydrosilylation o f ketoximes to give the corresponding primary amines in good yields with hi gh enantioselectivities (up to 89% ee) after acid hydrolysis.