Studies on the BF3 center dot Et2O/MCM-41 solid acid catalyst and its catalytic performance

Authors
Zhou, RX Mo, LY Zhao, SF Wang, YJ Zheng, XM
Citation
Rx. Zhou et al., Studies on the BF3 center dot Et2O/MCM-41 solid acid catalyst and its catalytic performance, CHEM J CH U, 22(9), 2001, pp. 1576-1577
Citations number
3
Categorie Soggetti
Chemistry
Journal title
CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE
ISSN journal
02510790 → ACNP
Volume
22
Issue
9
Year of publication
2001
Pages
1576 - 1577
Database
ISI
SICI code
0251-0790(200109)22:9<1576:SOTBCD>2.0.ZU;2-C
Abstract
A solid acid catalyst has been prepared by grafting Boron trifluoride on me soporous molecular sieve MCM-41 and characterized by XRD and FTIR technique s. The XRD and FTIR results indicated that the (BF3Et2O)-Et-. interlocks wi th the silicon groups of MCM-41 surface to form strong solid acid. The soli d acid catalyst would effectively promote the opening of epichlorohydrin wi th isobutanol to form 1-isobutoxy-3-chloropropanol, and showed a nice activ ity and selectivity.