Soot formation is still one of the most pressing problems in combustion. Ch
emical mechanisms have been established which need to be examined in detail
under laboratory conditions. Some of the main pathways concerning the form
ation of soot precursors are still under debate. While it seems commonly ac
cepted that some of the dominant routes may be fuel-specific. experimental
data and their comparison with kinetic models for fuels with more than 3 C
atoms are scarce. This article will present an overview of the work pursued
in Bielefeld on the characterisation of fuel-rich flames by a combination
of laser spectroscopy and mass spectrometry. (C) 2001 Academie des sciences
/Editions scientifiques et medicales Elsevier SAS.