Thermal and nonlinear optical properties of Ca4YO(BO3)(3)
Citation
J. Luo et al., Thermal and nonlinear optical properties of Ca4YO(BO3)(3), CRYST RES T, 36(11), 2001, pp. 1215-1221
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
CRYSTAL RESEARCH AND TECHNOLOGY
SICI code
0232-1300(2001)36:11<1215:TANOPO>2.0.ZU;2-D
Abstract
Ca4YO(BO3)(3) (YCOB) crystals have been grown using the vertical Bridgman m
ethod. The thermal properties of YCOB were measured for the First time to o
ur knowledge. The specific heat is 729.7 J/kg K at 373K. The average therma
l expansion coefficients along the a, b and e axes are 9.9x10(-6) K, 8.2x10
(-6) /K and 12.8x10(-6) K, respectively, in the temperature range of 293-11
73K. The thermal conductivities along the a, b and c axes are 1.83W/mK, 1.7
2W/mK and 2.17W/mK at 373K. The anisotropy in the measured thermal conducti
vties of YCOB is consistent with the experimental results of the thermal ex
pansion. The SIM of a Nd: YAG laser was compared with that of a KDP crystal
. The effective nonlinear coefficients (d(ctt)) of YCOB in type I phase mat
ching directions of (0, phi)=(66.3 degrees. 143.5 degrees) and (65.9 degree
s, 36.5 degrees) were estimated to be 1.45pm/V and 0.91pm/V, respectively.
The bulk damage threshold was observed as 85GW/cm(2) for single Pulse of a
Nd:YAG laser with 10ns Pulse duration.