The title compound (6,6-dimethyl-cis-6H,6aH,7H,12bH,13H-bis[1] benzopyrano[
4,3-b:4 ' ,3 ' -d]pyran-13-one) crystallizes in monoclinic space group P2(1
)/c with Z = 4. The unit cell dimensions are a = 8.6231(2) Angstrom, b = 10
.0260(2) Angstrom, c = 19.8376(2) Angstrom, and beta = 102.1(1)degrees, V =
1674.51(5) Angstrom (3), D-cal = 1.326 Mg/m(3). The coumarin moiety is in
the planar conformation, the dioxadecalin moiety is cis fused and within th
e dioxadecalin moiety both the rings are in half cahir/sofa conformations.
The structure has many C-H...O type interactions.