The recent implementation of gas-filled radiofrequency traps for efficient
ion beam bunching extended the applicability of the Penning trap mass spect
rometer ISOLTRAP/CERN to non-surface ionizable species. In a first series o
f successful runs the masses of Hg182-197, Pb-196,Pb-198, Bi-197, Po-198 an
d At-203 have been determined with an accuracy of 1 . 10(-7). In order to u
nambiguously determine the ground state mass the ground and isomeric states
of Hg-185,Hg-187,Hg-191,Hg-193,Hg-197 were separated applying a resolving
power of up to 3.7 . 10(6). First experimental values for the isomeric exci
tation energy of Hg-187,Hg-191 were obtained.