J. Tao et al., A new inorganic-organic photoluminescent material constructed with helical[Zn-3(mu(3)-OH)(mu(2)-OH)] chains, INORG CHEM, 40(24), 2001, pp. 6328
A New Inorganic-Organic Photoluminescent Material Constructed with Helical
[Zn-3(mu (3)-OH)(mu (2)-OH)] Chains A photoluminescent inorganic-organic ma
terial formulated as [Zn-3(mu (3)-OH)(mu (2)-OH)(4,4'-bpy)(0.5)-(4,4'-oba)(
2)].0.5H(2)O (4,4'-bpy = 4,4'-bipyridine; 4,4'-oba = 4,4'-oxybis(benzoate))
, shown by X-ray diffraction, features a novel polynuclear zinc helical cha
in motif. Linkage of mixed organic ligands and helical chains results in a
3-D network.