Phosphite derivatives of (2R)-2-pyrrolidin-1-yl-butan-1-ol: synthesis, chelation with rhodium(I) and testing in the palladium-catalysed allylic alkylation

Authors
Polosukhin, AI Bondarev, OG Korostylev, AV Hilgraf, R Davankov, VA Gavrilov, KN
Citation
Ai. Polosukhin et al., Phosphite derivatives of (2R)-2-pyrrolidin-1-yl-butan-1-ol: synthesis, chelation with rhodium(I) and testing in the palladium-catalysed allylic alkylation, INORG CHIM, 323(1-2), 2001, pp. 55-61
Citations number
25
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
INORGANICA CHIMICA ACTA
ISSN journal
00201693 → ACNP
Volume
323
Issue
1-2
Year of publication
2001
Pages
55 - 61
Database
ISI
SICI code
0020-1693(20011029)323:1-2<55:PDO(SC>2.0.ZU;2-A
Abstract
A series of chiral phosphite-type ligands with pyrrolidine moieties was syn thesised. The compounds form chelate complexes upon reaction with [Rh(CO)(2 )Cl](2). The new ligands were tested in Pd-catalysed enantioselective allyl ic alkylation giving up to 61% ee under standard conditions. (C) 2001 Elsev ier Science B.V. All rights reserved.