Semi-interpenetrating polymer networks were synthesized starting from polyu
rethane (PU) and epoxy maleate of bisphenol A (EMBA). Differential scanning
calorimetry and swelling measurements showed good miscibility and the pres
ence of the strong intermolecular interactions within the synthesized netwo
rks. The physicomechanical properties increased against PU to a maximum val
ue with the increasing of EMBA content up to 12 wt % and then decreased wit
h further increasing EMBA content. Generally, with exception of the elongat
ion at the limit of elasticity, the mechanical properties improved very muc
h under action of the UV radiation. (C) 2002 John Wiley & Sons, Inc.