Preparation of an insoluble polymer-supported Mn (III) porphyrin and its use as a new alkene epoxidation and alkane hydroxylation catalyst

Authors
Tangestaninejad, S Habib, MH Mirkhani, V Moghadam, M
Citation
S. Tangestaninejad et al., Preparation of an insoluble polymer-supported Mn (III) porphyrin and its use as a new alkene epoxidation and alkane hydroxylation catalyst, J CHEM R-S, (10), 2001, pp. 444-445
Citations number
33
Categorie Soggetti
Chemistry
Journal title
JOURNAL OF CHEMICAL RESEARCH-S
ISSN journal
03082342 → ACNP
Issue
10
Year of publication
2001
Pages
444 - 445
Database
ISI
SICI code
0308-2342(200110):10<444:POAIPM>2.0.ZU;2-7
Abstract
An easy and effective method to prepare a new supported Mn(III)-porphyrin b y immobilisation of Mn(III)-5,10,15, 20-Tetrakis(p-sulfonatophenyl)porphyri n, [Mn(TPPS)], on poly(4-styrylmethyl)pyridinium chloride (PSMP) is reporte d. This catalyst was found to be efficient for catalysing alkene epoxidatio n and alkane hydroxylation with sodium periodate. This new heterogenised me talloporphyrin catalyst is of high stability and reusability.