Vibrational spectroscopic study of [1,2-bis(4-pyridyl)ethane]metal(II) tetracyanonickelate(II). 2 m-xylene clathrates

Authors
Tufan, Y Karacan, N OzdemIr, U
Citation
Y. Tufan et al., Vibrational spectroscopic study of [1,2-bis(4-pyridyl)ethane]metal(II) tetracyanonickelate(II). 2 m-xylene clathrates, J INCL P MA, 40(4), 2001, pp. 275-278
Citations number
14
Categorie Soggetti
Chemistry
Journal title
JOURNAL OF INCLUSION PHENOMENA AND MACROCYCLIC CHEMISTRY
ISSN journal
13883127 → ACNP
Volume
40
Issue
4
Year of publication
2001
Pages
275 - 278
Database
ISI
SICI code
1388-3127(200108)40:4<275:VSSO[T>2.0.ZU;2-0
Abstract
Four new Hofmann-type clathrates of the form M(bpa)(2)Ni(CN)(4). 2m-xylene (M = Mn , Fe , Co and Ni; bpa = 1,2-bis(4-pyridyl)ethane) have been synthes ized and characterized by vibrational spectroscopy. The M(bpa)(2)Ni(CN)(4) (M = Fe and Co) host structure is similar to the classical Hofmann-type hos t framework composed of layers of a two dimensional catena-metal tetra-mu - cyanonickelate(II) network, but in M(bpa)(2)Ni(CN)(4) (M = Mn and Ni), the Ni(CN)(4) moiety behaves as a bidentate -[NC-Ni(CN)(2)-CN-]- unit in the ho st framework.