Due to the slow cooling rate in the alloying furnace, large amount of britt
le precipitates appear in the alloyed layers which are formed by the DGPSA
(Double Glow Plasma Surface Alloying) with tungsten-molybdenum. It causes t
he mechanical properties of the samples to be seriously degraded. Qualitati
ve phase analysis reveals that they are mainly composed of the p-phase, and
a small amount of carbide, M6C. In this paper the microstructure and therm
odynamic factors of the precipitates are exhaustively investigated. There a
re two transformation noses in the isothermal transformation (IT) diagram o
f the precipitates. As a major object of this work, an effective measure is
offered to depress the deposition of the precipitates.