Electrochemical behavior of heteropoly acid anions adsorbed in electrodes modified with mesoporous molecular sieve silica

Authors
Li, WJ Wang, ZC Sun, CQ Zhao, MY Yao, YW Cui, AL
Citation
Wj. Li et al., Electrochemical behavior of heteropoly acid anions adsorbed in electrodes modified with mesoporous molecular sieve silica, J MAT SCI T, 17, 2001, pp. S131-S134
Citations number
18
Categorie Soggetti
Material Science & Engineering
Journal title
JOURNAL OF MATERIALS SCIENCE & TECHNOLOGY
ISSN journal
10050302 → ACNP
Volume
17
Year of publication
2001
Supplement
1
Pages
S131 - S134
Database
ISI
SICI code
1005-0302(2001)17:<S131:EBOHAA>2.0.ZU;2-T
Abstract
Heteropoly acid H4SiW12O48 (denoted as SiW12) was assembled with the mesopo rous materials MCM-41 modified with 3-aminopropyltriethoxysilane (APTES) (d enote MCM-41((m))). The electrochemical behavior of SiW12/MCM-41((m)) compl exes-based electrode indicated SiW12 anion was adsorbed by MCM-41((m)). In MCM-41((m)) electrode, large voltammetric waves, showing that the electrost atic bound ions adsorbed in MCM-41((m)) were electrochemically active. The potential application as amperometric sensors for nitrite is anticipated.