Dendralene-type TTF vinylogs containing a 1,3-diselenole ring

Citation
Rr. Amaresh et al., Dendralene-type TTF vinylogs containing a 1,3-diselenole ring, J ORG CHEM, 66(23), 2001, pp. 7757-7764
Citations number
10
Categorie Soggetti
Chemistry & Analysis","Organic Chemistry/Polymer Science
Journal title
JOURNAL OF ORGANIC CHEMISTRY
ISSN journal
00223263 → ACNP
Volume
66
Issue
23
Year of publication
2001
Pages
7757 - 7764
Database
ISI
SICI code
0022-3263(20011116)66:23<7757:DTVCA1>2.0.ZU;2-Q
Abstract
2-Diformylmethylene-1,3-diselenole was prepared and condensed with dithioli um phoshonium bromides and dithiolium phosphonates in the presence of base to. give dendralene-type vinylogs of TTF bearing a 1,3-diselenole moiety. T he electrochemistry of these dendrimers was studied. SEEPR measurements wer e also carried out. Calculations were carried out on the radical cations an d correlated with the EPR values.