Oxidative esterification of alkenes via pi- and sigma-organopalladium complexes: new pathways for the reaction

Authors
Kozitsyna, NY Bukharkina, AA Martens, MV Vargaftik, MN Moiseev, II
Citation
Ny. Kozitsyna et al., Oxidative esterification of alkenes via pi- and sigma-organopalladium complexes: new pathways for the reaction, J ORGMET CH, 636(1-2), 2001, pp. 69-75
Citations number
17
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
JOURNAL OF ORGANOMETALLIC CHEMISTRY
ISSN journal
0022328X → ACNP
Volume
636
Issue
1-2
Year of publication
2001
Pages
69 - 75
Database
ISI
SICI code
0022-328X(20011125)636:1-2<69:OEOAVP>2.0.ZU;2-T
Abstract
New mechanistic data on the oxidative esterification of alkenes were obtain ed in the study of the reaction of Pd(II) acetate with hex-1-ene, methylcyc lohex-1-ene and racemic a-pinene in a chloroform solution. High yields of u nsaturated esters with terminal alcohol group were found in the oxidation o f hex-l-ene, while the exocyclic methyl groups in methyleyclohex-1-ene and a-pinene remain untouched. (C) 2001 Elsevier Science B.V. All rights reserv ed.