Degradation of a methacrylate-substituted oxozirconium cluster by acetylacetone

Authors
Moraru, B Kickelbick, G Battistella, M Schubert, U
Citation
B. Moraru et al., Degradation of a methacrylate-substituted oxozirconium cluster by acetylacetone, J ORGMET CH, 636(1-2), 2001, pp. 172-174
Citations number
7
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
JOURNAL OF ORGANOMETALLIC CHEMISTRY
ISSN journal
0022328X → ACNP
Volume
636
Issue
1-2
Year of publication
2001
Pages
172 - 174
Database
ISI
SICI code
0022-328X(20011125)636:1-2<172:DOAMOC>2.0.ZU;2-P
Abstract
Reaction of Zr4O2(OMc)(12) (OMc = methacrylate) with acetylacetone leads to the degradation of the cluster and formation of monomeric Zr(acac)(2)(OMc) (2) (acac = acetylacetonate). The zirconium atom in Zr(acac)(2)(OMc)(2) is dodecahedrally coordinated by the eight oxygen atoms of the chelating OMc a nd acac ligands. (C) 2001 Elsevier Science B.V. All rights reserved.