Unexpectedly, the product analysis in microwave CH4/O-2 discharge by Li+ io
n attachment mass spectrometry has brought forth a detection in the formati
on of the hydrogen peroxide H2O2. Furthermore, the observation of the minor
H2O2H+ peak gives indirect evidence of H2O2 formation. The studies have be
en done in terms of discharge conditions with a view of increasing the prod
uct rate and to confirm the possible production of this compound in the gas
phase.