The calculation and measurement of the properties of thermal plasmas in mix
tures of different gases are reviewed. The calculation of composition, ther
modynamic properties and transport coefficients is described. Particular at
tention is given to the calculation of diffusion coefficients, which is a s
ignificant problem in mixed-gas plasmas. The combined diffusion coefficient
formulation is shown to be a useful method for the treatment of diffusion.
Computational fluid dynamic modelling of thermal plasmas in gas mixtures i
s considered, using the examples of demixing in welding arcs, the turbulent
mixing of atmospheric air into a plasma jet and a plasma waste destruction
process. Diagnostic techniques for mixed-gas plasmas, in particular emissi
on spectroscopy, laser scattering and laser-induced fluorescence, are discu
ssed.