Zirconia ferrules for optical connectors were examined after aging at 85 de
greesC and 95% relative humidity. Two degradation mechanisms were the rough
ening and the deformation of the zirconia ferrule surface. Raman microscopy
revealed that this relatively low-temperature degradation of zirconia ferr
ules is caused by the tetragonal to monoclinic transformation of zirconia,
and is accelerated by stress relief during polishing. The surface upheavals
associated with low-temperature aging may significantly degrade the perfor
mance of optical connectors over time.