J. Taraci et al., Synthesis of silicon-based infrared semiconductors in the Ge-Sn system using molecular chemistry methods, J AM CHEM S, 123(44), 2001, pp. 10980-10987
Growth reactions based on a newly developed deuterium-stabilized Sn hydride
[(Ph)SnD3] with Ge2H6 produce a new family of Ge-Sn semiconductors with tu
nable band gaps and potential applications in high-speed, high-efficiency i
nfrared optoelectronics. Metastable diamond-cubic films of Ge1-xSnx alloys
are created by chemical vapor deposition at 350 degreesC on Si(100). These
exhibit unprecedented thermal stability and superior crystallinity despite
the 17% lattice mismatch between the constituent materials. The composition
, crystal structure, electronic structure, and optical properties of these
materials are characterized by Rutherford backscattering, high-resolution e
lectron microscopy, and X-ray diffraction, as well as Raman, IR, and spectr
oscopic ellipsometry. Electron diffraction reveals monocrystalline and perf
ectly epitaxial layers with lattice constants intermediate between those of
Ge and a-Sn. X-ray diffraction in the theta -2 theta mode shows well-defin
ed peaks corresponding to random alloys, and in-plane rocking scans of the
(004) reflection confirm a tightly aligned spread of the crystal mosaics. R
BS ion-channeling including angular scans confirm that Sn occupies substitu
tional lattice sites and also provide evidence of local ordering of the ele
ments with increasing Sn concentration. The Raman spectra show bands corres
ponding to Ge-Ge and Sn-Ge vibrations with frequencies consistent with rand
om tetrahedral alloys. Resonance Raman and ellipsometry spectra indicate a
band-gap reduction relative to Ge. The IR transmission spectra suggest that
the band gap decreases monotonically with increasing Sn fraction. The synt
hesis, characterization, and gas-phase electron diffraction structure of (P
h)SnD3 are also reported.