The role of Bronsted acid catalysis in inter-metal ligand exchange reactions

Authors
Blackmore, IJ Gibson, VC Graham, AJ Jolly, M Marshall, EL Ward, BP
Citation
Ij. Blackmore et al., The role of Bronsted acid catalysis in inter-metal ligand exchange reactions, J CHEM S DA, (22), 2001, pp. 3242-3243
Citations number
19
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS
ISSN journal
14727773 → ACNP
Issue
22
Year of publication
2001
Pages
3242 - 3243
Database
ISI
SICI code
1472-7773(2001):22<3242:TROBAC>2.0.ZU;2-U
Abstract
A Bronsted acid is shown to catalyse the inter-metal exchange of mono-anion ic (alkoxide and amide) and dianionic (imido) ligands in four-coordinate mo lybdenum complexes of the type Mo(NR)(2)(X)(2) (R = alkyl, aryl; X = alkoxi de, amide).