Synthesis and applications to asymmetric catalysis of a series of mono- and bis(diazaphospholidine) ligands

Authors
Smyth, D Tye, H Eldred, C Alcock, NW Wills, M
Citation
D. Smyth et al., Synthesis and applications to asymmetric catalysis of a series of mono- and bis(diazaphospholidine) ligands, J CHEM S P1, (21), 2001, pp. 2840-2849
Citations number
57
Categorie Soggetti
Chemistry & Analysis","Organic Chemistry/Polymer Science
Journal title
JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1
ISSN journal
14727781 → ACNP
Issue
21
Year of publication
2001
Pages
2840 - 2849
Database
ISI
SICI code
1472-7781(20011107):21<2840:SAATAC>2.0.ZU;2-I
Abstract
The synthesis of a series of closely related mono- and bis(diazaphospholidi ne) ligands has been achieved using the condensation of a diamine with a bi s(dimethylamino)arylphosphine. The resulting ligands have given excellent r esults in palladium-catalysed allylic substitution reactions to form C-C bo nds (up to 89% ee) and C-N bonds (up to 78% ee).