Synthesis of (R)-{eta(6)-[O-methyl-N-(alpha-methylbenzyl)hydroxyamino]-benzene} chromium tricarbonyl via nucleophilic aromatic substitution of (eta(6)-fluorobenzene) chromium tricarbonyl

Authors
da Costa, MRG Curto, MJM Davies, SG Sanders, J Teixeira, FC
Citation
Mrg. Da Costa et al., Synthesis of (R)-{eta(6)-[O-methyl-N-(alpha-methylbenzyl)hydroxyamino]-benzene} chromium tricarbonyl via nucleophilic aromatic substitution of (eta(6)-fluorobenzene) chromium tricarbonyl, J CHEM S P1, (21), 2001, pp. 2850-2855
Citations number
60
Categorie Soggetti
Chemistry & Analysis","Organic Chemistry/Polymer Science
Journal title
JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1
ISSN journal
14727781 → ACNP
Issue
21
Year of publication
2001
Pages
2850 - 2855
Database
ISI
SICI code
1472-7781(20011107):21<2850:SO(>2.0.ZU;2-I
Abstract
Chiral hydroxylamine chromium tricarbonyl complexes may be prepared in sati sfactory to reasonable yield via nucleophilic aromatic substitution of the anion derived from N,O-substituted hydroxylamines and (eta (6)-fluorobenzen e) chromium tricarbonyl. The enantiomerically pure complex (R)-{eta (6)-[O- methyl-N-(alpha -methylbenzyl)hydroxyamino]benzene} chromium tricarbonyl 6a was characterised by X-ray crystallography.