Synthesis of dihydrobenzazaphosphole ligands via an intramolecular cyclisation reaction

Authors
Leung, W Cosway, S Jones, RHV McCann, H Wills, M
Citation
W. Leung et al., Synthesis of dihydrobenzazaphosphole ligands via an intramolecular cyclisation reaction, J CHEM S P1, (20), 2001, pp. 2588-2594
Citations number
18
Categorie Soggetti
Chemistry & Analysis","Organic Chemistry/Polymer Science
Journal title
JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1
ISSN journal
14727781 → ACNP
Issue
20
Year of publication
2001
Pages
2588 - 2594
Database
ISI
SICI code
1472-7781(20011021):20<2588:SODLVA>2.0.ZU;2-O
Abstract
A novel intramolecular cyclisation reaction of 1,3,2-oxazaphospholidines ha s been employed for the diastereoselective synthesis of chiral, non-racemic dihydrobenzazaphosphole ligands. The new ligands. have been employed in en antioselective palladium-catalysed allylic substitution-reactions.