Benzotriazole maleimide as a bifunctional reactant for SERS

The synthesis of a benzotriazole maleimide is reported and its use as a bif unctional compound demonstrated. The triazole moiety of the compound comple xes strongly with metals such as copper and silver and can be used to form monolayers on metal surfaces. The maleimide acts as a dienophile and reacts with dienes to produce cycloadducts. We report the selective reaction of t he benzotriazole maleimide with seven different dienes to produce a range o f cycloadducts. These cycloadducts were then adsorbed onto a metal surface via the triazole group. The presence on the metal surface was confirmed by surface enhanced Raman scattering, SERS. SERS is a vibrational spectroscopy and as such provides a fingerprint of each compound examined. The cycloadd ucts all gave different spectra that allowed identification of each diene t hat had cyclised. The dienes did not produce SERS on their own and had to b e reacted with the bifunctional benzotriazole maleimide prior to examinatio n. This provides an illustration of the use of bifunctional reactants speci fically designed to produce SERS active products and also provides an examp le of an efficient derivatisation chemistry for copper and silver metal sur faces.