In this study, direct numerical simulations (DNS) of a 2D fully-developed t
urbulent open-channel flow were performed. Numerical investigations were ca
rried out for two Prandtl (Schmidt) numbers 1.0 and 5.0, with a Reynolds nu
mber of 200, based on the friction velocity and flow depth. The budgets of
the Reynolds stresses and the effects of the free-surface turbulence on the
scalar transport were mainly investigated. The results were that typical t
urbulence structures affected by the presence of the free surface appeared
in the 5% region from the free surface. The effect of these free-surface tu
rbulent structures on the fundamental turbulent quantities is not important
because the free surface does not contribute to the turbulence generation
in the open-channel flow without surface deformation. However, heat transfe
r across the free surface was enhanced by a large horizontal vortex and the
flow depth scale was also affected by this free-surface turbulent structur
e. In the case of a scalar field with Pr = 5.0, besides this large horizont
al vortex, a high filamentary fragment exists because the time scale of the
fluid motion is so fast compared to the scalar diffusion time scale. Moreo
ver, the high wavenumber fluctuation effect on the scalar transport is larg
er than the scalar field of Pr = 1.0. These indicate that the Reynolds anal
ogy between momentum and scalar transport cannot be applied to high Prandtl
or Schmidt number fluids. Consequently, for the accurate prediction of sca
lar quantities near free-surface turbulence models based on the unsuitable
assumption should be modified in the high Prandtl (Schmidt) number fluids.