Effect of poly(ethylene glycol)s on micellar stability of sodium dodecyl sulfate

Authors
Citation
D. Dhara et Do. Shah, Effect of poly(ethylene glycol)s on micellar stability of sodium dodecyl sulfate, LANGMUIR, 17(23), 2001, pp. 7233-7236
Citations number
22
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
LANGMUIR
ISSN journal
07437463 → ACNP
Volume
17
Issue
23
Year of publication
2001
Pages
7233 - 7236
Database
ISI
SICI code
0743-7463(20011113)17:23<7233:EOPGOM>2.0.ZU;2-T
Abstract
The effects of poly(ethylene glycol)s of different molecular weights on the micellar stability of sodium dodecyl sulfate in the concentration range fr om 50 to 600 mM were investigated. The presence of polymer was found to dec rease micellar stability drastically. The decreased stability of micelles i s explained by the increased population of small aggregates in the presence of polymer. This decreases the value of "resistance" for the micellar form ation-dissolution process. The foaming property of SDS solutions in the pre sence of poly(ethylene glycol) was related to micellar stability.