The effects of poly(ethylene glycol)s of different molecular weights on the
micellar stability of sodium dodecyl sulfate in the concentration range fr
om 50 to 600 mM were investigated. The presence of polymer was found to dec
rease micellar stability drastically. The decreased stability of micelles i
s explained by the increased population of small aggregates in the presence
of polymer. This decreases the value of "resistance" for the micellar form
ation-dissolution process. The foaming property of SDS solutions in the pre
sence of poly(ethylene glycol) was related to micellar stability.