New heterocyclic precursors for thermal generation of reactive, electron-rich 1,2-diaza-1 3-butadienes

Authors
Boeckman, RK Ge, P Reed, JE
Citation
Rk. Boeckman et al., New heterocyclic precursors for thermal generation of reactive, electron-rich 1,2-diaza-1 3-butadienes, ORG LETT, 3(23), 2001, pp. 3647-3650
Citations number
31
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
ORGANIC LETTERS
ISSN journal
15237060 → ACNP
Volume
3
Issue
23
Year of publication
2001
Pages
3647 - 3650
Database
ISI
SICI code
1523-7060(20011115)3:23<3647:NHPFTG>2.0.ZU;2-6
Abstract
[GRAPHICS] The preparation and thermolysis of new stable heterocyclic precursors of 1, 2-diaza-1,3-butadienes is described. The resulting reactive diazadienes are trapped in situ with N-phenyldiazamaleimide. The effect of precursor struc ture on the temperature at which the diazadienes are generated is discussed .