Lithium sulfonated styrene oligomer (LiSSO) as a new class of lithium saltfor polymer electrolytes

Authors
Lee, YG Kim, CH Park, JK Seung, DY
Citation
Yg. Lee et al., Lithium sulfonated styrene oligomer (LiSSO) as a new class of lithium saltfor polymer electrolytes, POLYM BULL, 47(2), 2001, pp. 167-174
Citations number
23
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
POLYMER BULLETIN
ISSN journal
01700839 → ACNP
Volume
47
Issue
2
Year of publication
2001
Pages
167 - 174
Database
ISI
SICI code
0170-0839(200110)47:2<167:LSSO(A>2.0.ZU;2-1
Abstract
A new class of lithium salt with single-ionic characteristics, lithium sulf onated styrene oligomer (LiSSO) [(CH2CHC6H5)(7)-(CH2CHC6H4SO3-Li+)(2)], was synthesized and its complex with poly(ethylene oxide) (PEO) was prepared. The maximum ionic conductivity of the PEO/LiSSO complex at 65 degreesC was 2.1 x 10(-4) S/cm at a salt concentration of [Li+]/[EO] = 0.20. The lithium cationic transference number (t(+)) of the PEO/LiSSO complex was found to be 0.95, and the polymer electrolyte was electrochemically stable up to 6.2 V.