Kinetic parameters for the sorption of ions during multicomponent ion exchange

Citation
Si. Karpov et al., Kinetic parameters for the sorption of ions during multicomponent ion exchange, RUSS J PH C, 75(11), 2001, pp. 1851-1855
Citations number
15
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
RUSSIAN JOURNAL OF PHYSICAL CHEMISTRY
ISSN journal
00360244 → ACNP
Volume
75
Issue
11
Year of publication
2001
Pages
1851 - 1855
Database
ISI
SICI code
0036-0244(200111)75:11<1851:KPFTSO>2.0.ZU;2-V
Abstract
The kinetics of sorption of ions in three-component ion exchange is discuss ed. An expression for the ion fluxes of the components and apparent diffusi on coefficients of the sorbed ions with regard for the mutual action of the mobilities of the sorbed and desorbed ions was obtained. For a nonselectiv e ion exchange, the magnitude and direction of the flux depend on the ratio between the apparent diffusion coefficients. Knowledge of these quantities and the relations between them makes it possible to predict the shape of t he kinetic curves.