Stereoselective preparation of (E)-epsilon-nitro-beta,gamma-unsaturated unsaturated methyl esters: Amberlyst A 27, using microwave, as superior catalyst for the 1,6-conjugate addition of nitroalkanes to methyl 1,3-butadiene-1-carboxylate

Authors
Ballini, R Bosica, G Fiorini, D
Citation
R. Ballini et al., Stereoselective preparation of (E)-epsilon-nitro-beta,gamma-unsaturated unsaturated methyl esters: Amberlyst A 27, using microwave, as superior catalyst for the 1,6-conjugate addition of nitroalkanes to methyl 1,3-butadiene-1-carboxylate, TETRAHEDR L, 42(48), 2001, pp. 8471-8473
Citations number
16
Categorie Soggetti
Chemistry & Analysis","Organic Chemistry/Polymer Science
Journal title
TETRAHEDRON LETTERS
ISSN journal
00404039 → ACNP
Volume
42
Issue
48
Year of publication
2001
Pages
8471 - 8473
Database
ISI
SICI code
0040-4039(20011126)42:48<8471:SPO(U>2.0.ZU;2-Y
Abstract
1,6-Conjugate addition of nitroalkanes to methyl 1,3-b-atadiene-1-carboxyla te, performed with Amberlyst A 27, using microwaves and in the absence of a ny solvent, allows the prevalent formation of the beta,gamma -unsaturated a dduct, over the alpha,beta -unsaturated one. The products were exclusively obtained as (E)-isomers. (C) 2001 Elsevier Science Ltd. All rights reserved .