1,3-bis(4-methoxyphenyl)cyclohexane-1,3-diyl cation radical: divergent reactivity depending upon electron-transfer conditions

Authors
Ikeda, H Hoshi, Y Miyashi, T
Citation
H. Ikeda et al., 1,3-bis(4-methoxyphenyl)cyclohexane-1,3-diyl cation radical: divergent reactivity depending upon electron-transfer conditions, TETRAHEDR L, 42(48), 2001, pp. 8485-8488
Citations number
14
Categorie Soggetti
Chemistry & Analysis","Organic Chemistry/Polymer Science
Journal title
TETRAHEDRON LETTERS
ISSN journal
00404039 → ACNP
Volume
42
Issue
48
Year of publication
2001
Pages
8485 - 8488
Database
ISI
SICI code
0040-4039(20011126)42:48<8485:1CRDR>2.0.ZU;2-R
Abstract
1,3-Bis(4-methoxyphenyl)cyclohexane-1,3-diyl cation radical aves 1,5-bis(4- methoxyphenyl)bicyclo[3.1.0]hexane through 1,3-bis(4-nictlioxyphenyl)cycloh exine-1,3-diyl when generated by photoinduced electron transfer, but gives 4,4 " -dimethoxy-m-terphenyl when generated by using one-electron oxidant, demonstrating its divergent reactivity depending upon the electron-transfer conditions employed. (C) 2001 Elsevier Science Ltd. All rights reserved.