(Fluoroorgano)fluoroboranes and -fluoroborates. 2. Synthesis and spectroscopic characterization of potassium polyfluoroalken-1-yltrifluoroborates

Authors
Frohn, HL Bardin, VV
Citation
Hl. Frohn et Vv. Bardin, (Fluoroorgano)fluoroboranes and -fluoroborates. 2. Synthesis and spectroscopic characterization of potassium polyfluoroalken-1-yltrifluoroborates, Z ANORG A C, 627(11), 2001, pp. 2499-2505
Citations number
21
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE
ISSN journal
00442313 → ACNP
Volume
627
Issue
11
Year of publication
2001
Pages
2499 - 2505
Database
ISI
SICI code
0044-2313(200111)627:11<2499:(A-2SA>2.0.ZU;2-4
Abstract
(T)he potassium fluoroborates K[RCF=CFBF3] (R = F, Cl (cis-/trans-mixture), trans-C4F9, cis-C2F5, cisC(6)F(13), trans-C4H9, trans-C6H5) were prepared by fluoridation (methoxide-fluoride substitution with K[HF2]) of RCF=CFB(OM e)(2) and Li[RCF=CFB(OMe)(3)] which were obtained from RCF=CFLi and B(OMC)( 3). The K[RCF=CFBF3] salts were characterized by their H-1, B-11, F-19 NMR and IR spectra.