The BC2N thin films in stalklike growth have been deposited by hot filament
assisted and rf plasma chemical vapor deposition (CVD). It was shown that
the composition of the thin films mainly consists of BC2N, in which B, C an
d N were combined in atomic bonds. And the surface of the film took the sha
pe of stalks, they were in regular arrangement with a uniform orientation o
bserved with scanning electron microscopy. In addition, we found this kind
of growth had intimate relation with the deposition parameters. Finally, we
analyzed the growth machanism of the stalklike BC2N.