The effect of substituting calcium aluminate cement with different proporti
ons (4, 7, and 9 wt-%) of fine calcined alumina (< 40 mum) on the physico-m
echanical properties of self-forming MA spinet castables was studied. The 7
day hydrated samples (cured at 20 degreesC) were fired at different temper
atures (800, 1400, 1500, and 1550 degreesC) and their mineralogical composi
tion and microstructure investigated using XRD and SEM methods, The densifi
cation parameters and cold crushing strength of the fired samples were also
measured and cot-related with their mineralogical compositions and microst
ructure. The results reveal that castable samples with 9 wt-% fine alumina
and fired at 1550 degreesC were found to give improved physico-mechanical p
roperties (bulk density = 2.39 g cm(-3), apparent porosity = 7.04%, and col
d crushing strength = 95.9 MPa) due to the formation of intertwined three-d
imensional hexagonal plate-like crystals of CA(6) that improve the. mechani
cal properties.