Furan-resin-derived carbon generally produces a glass-like carbon having en
tangled graphene layers (graphite structure) after high temperature heat-tr
eatments. However, Raman spectroscopy reveals that it produces well-graphit
ized thin skins on surfaces. The graphitization is promoted on the faces th
at are formed at lower heat-treatment temperatures. Fractured faces of spec
imens pre-heat-treated at 1000 degreesC result in well-developed structures
in graphitization after re-heat-treatment at 3000 degreesC. It is consider
ed that the surfaces, i.e. free faces, play an important role in the graphi
tization. (C) 2001 Elsevier Science Ltd. All rights reserved.