Effect of precipitant on the performances and structures of Au/ZnO catalysts for CO oxidation

Various Au/ZnO catalysts were prepared by a coprecipitation method with fou r kinds of precipitants, Na2CO3 (NH4)(2)CO3, NaOH and NH4OH, and the cataly tic performance of CO oxidation at an ambient temperature and humidity were studied. It was found that the precipitants play an important role for the Au/ZnO catalyst structure, such as the precursors, the particle size of Zn O and metallic gold and the BET surface area of Au/ZnO catalysts. The sampl e prepared by using NH4OH as precipitant exhibited a lower activity and poo rer stability, while the Au/ZnO catalysts prepared by other three precipita nts can maintain CO completely oxidized to CO2 for at least 1 100 h. The fe ed gas mixture can result in sintering of metallic gold and accumulation of carbonate-like species on the surface of Au/ZnO catalysts during the CO ox idation process. The stability is related to the rate of gold sintering and the amount of hydrozincite formed on the catalyst surface.