KINETICS OF THE OXIDATION OF THIOGLYCOLIC AND THIOMALIC ACIDS BY A NICKEL(III) OXIME-IMINE COMPLEX

Authors
DUTTA A SAHA B ALI M BANERJEE P
Citation
A. Dutta et al., KINETICS OF THE OXIDATION OF THIOGLYCOLIC AND THIOMALIC ACIDS BY A NICKEL(III) OXIME-IMINE COMPLEX, Journal of chemical research. Synopses, (6), 1997, pp. 186
Citations number
29
Categorie Soggetti
Chemistry
Journal title
Journal of chemical research. Synopses → ACNP
ISSN journal
03082342
Issue
6
Year of publication
1997
Database
ISI
SICI code
0308-2342(1997):6<186:KOTOOT>2.0.ZU;2-H
Abstract
The kinetics of the oxidation of thioglycolic and thiomalic acids by [ (NiL1)-L-III](2+) (where HL1 = ino-3-methyl-4,7,10,13-tetraazapentadec -3-en-2-one oxime) have been investigated at 30.0 degrees C; an inner- sphere mechanism for both the reactions has been proposed except for t he fully deprotonated species of thiomalic acid which follows an outer -sphere route.