Cn. Borca et al., Electronic-structure modifications induced by surface segregation in La0.65Pb0.35MnO3 thin lms, EUROPH LETT, 56(5), 2001, pp. 722-728
Using spin-polarized inverse photoemission and X-ray absorption spectroscop
y techniques, we show that the electronic structure of La0.65Pb0.35MnO3 thi
n lms depends on the composition at the surface. With a gentle annealing pr
ocedure, the surface provides a maximum of 80% spin asymmetry at 0.5 eV abo
ve the Fermi level in spite of extensive Pb segregation. A heavily annealed
( restructured) surface exhibits a reduced surface ordering temperature of
240 K ( compared to the approximately 335 K bulk value) as well as a reduc
ed spin asymmetry value of 40% at 0.5 eV above Fermi energy.