We have used first-principles linear muffin tin orbital (LMTO-ASA) electron
ic structure calculations, implemented directly in real space (RS) to theor
etically investigate the behavior of the hyperfine field of Co clusters emb
edded in fee Cu. We find that the magnitude of the dominant contact contrib
ution to the hyperfine field decreases significantly as one goes from the C
o site at the center of the cluster to those at the Co-Cu interface. To bet
ter understand this behavior, we use a simple model which closely reproduce
s the first-principles calculations, but is physically more transparent. Ou
r approach can partially deconvolute the several dependences, calling atten
tion to the processes which regulate the hyperfine field behavior in these
complex Co-Cu systems.