The influence of iodoacetic acid (IAA) on the corrosion inhibition of mild
steel in 0.5 M sulphuric acid (H2SO4) containing octylamine (OA) has been s
tudied using weightloss, polarization and a.c. impedence techniques. Corros
ion data obtained by different methods are consistent. IAA and OA individua
lly retard the corrosion of mild steel in sulphuric acid. The addition of I
AA enhances the inhibitor efficiency of OA considerably. Adsorption of inhi
bitors follows quasi-substitution process at the interfaces. OA cations are
adsorbed by coulombic interaction on the metal surface, which is preoccupi
ed by IAA molecules as dipoles. Adsorption model is suggested to account th
e synergistic action of IAA on the corrosion inhibition of mild steel in su
lphuric acid solution by OA.