Corrosion inhibition of mild steel in sulphuric acid by n-octylamine and iodoacetic acid

Citation
Ss. Begum et al., Corrosion inhibition of mild steel in sulphuric acid by n-octylamine and iodoacetic acid, I J CHEM T, 8(6), 2001, pp. 463-468
Citations number
17
Categorie Soggetti
Chemical Engineering
Journal title
INDIAN JOURNAL OF CHEMICAL TECHNOLOGY
ISSN journal
0971457X → ACNP
Volume
8
Issue
6
Year of publication
2001
Pages
463 - 468
Database
ISI
SICI code
0971-457X(200111)8:6<463:CIOMSI>2.0.ZU;2-U
Abstract
The influence of iodoacetic acid (IAA) on the corrosion inhibition of mild steel in 0.5 M sulphuric acid (H2SO4) containing octylamine (OA) has been s tudied using weightloss, polarization and a.c. impedence techniques. Corros ion data obtained by different methods are consistent. IAA and OA individua lly retard the corrosion of mild steel in sulphuric acid. The addition of I AA enhances the inhibitor efficiency of OA considerably. Adsorption of inhi bitors follows quasi-substitution process at the interfaces. OA cations are adsorbed by coulombic interaction on the metal surface, which is preoccupi ed by IAA molecules as dipoles. Adsorption model is suggested to account th e synergistic action of IAA on the corrosion inhibition of mild steel in su lphuric acid solution by OA.