The two significant types of emissions from fixed-roof storage tanks are "s
torage" and "working" losses. While the former arise from changes in enviro
nmental parameters, the latter result from liquid level changes in the tank
. Optimizing the storage policy requires the prediction of the influence of
the main operating parameters on the overall emissions. The aim of this wo
rk was to develop a mathematical model able to represent the main phenomena
involved in such emissions and to validate it by comparison with both labo
ratory-scale and real-size experimental data. Moreover, because semiempiric
al relations are available to estimate monthly or annual emissions, a compa
rison with these relations has been carried out both to further validate th
e model and to discuss the range of reliability of such relations.