Perovskite-type rare-earth rhodium borides of the chemical formula RRh3B (R
= La, Gd, Lu and Sc) have been studied from the viewpoint of microhardness
. Polycrystals of RRh3B are synthesized by the arc melting method. RRh3B co
mpounds have a perovskite-type cubic structure (space group: Pm (3) over ba
rm). The microhardness become larger with the contraction of the volume of
the Rb6B octahedron in the perovskite-type structure. As a result, microhar
dness increases with decreasing atomic size of R in RRh3B.