Thermodynamic properties of mixtures containing ionic liquids. 1. Activitycoefficients at infinite dilution of alkanes, alkenes, and alkylbenzenes in 4-methyl-n-butylpyridinium tetrafluoroborate using gas-liquid chromatography

Authors
Heintz, A Kulikov, DV Verevkin, SP
Citation
A. Heintz et al., Thermodynamic properties of mixtures containing ionic liquids. 1. Activitycoefficients at infinite dilution of alkanes, alkenes, and alkylbenzenes in 4-methyl-n-butylpyridinium tetrafluoroborate using gas-liquid chromatography, J CHEM EN D, 46(6), 2001, pp. 1526-1529
Citations number
19
Categorie Soggetti
Chemistry,"Chemical Engineering
Journal title
JOURNAL OF CHEMICAL AND ENGINEERING DATA
ISSN journal
00219568 → ACNP
Volume
46
Issue
6
Year of publication
2001
Pages
1526 - 1529
Database
ISI
SICI code
0021-9568(200111/12)46:6<1526:TPOMCI>2.0.ZU;2-0
Abstract
Activity coefficients at infinite dilution gamma (infinity)(i) of 19 alkane s, alkenes, and alkylbenzenes in the ionic liquid 4-methyl-n-butylpyridiniu m tetrafluoroborate (C10H16BF4N) were determined by gas chromatography usin g the ionic liquid as stationary phase. The measurements were carried out a t different temperatures between 313.1 K and 363.1 K. From the temperature dependence of the limiting activity coefficients partial molar excess entha lpies at infinite dilution H-i(E,infinity) of the organic solutes in the io nic liquids have been derived.