Phase equilibria of CFC alternative refrigerant mixtures. Binary systems of trifluoromethane (HFC-23)+1,1,1,2-tetrafluoroethane (HFC-134a) and trifluoromethane (HFC-23)+1,1,1,2,3,3,3-heptafluoropropane (HFC-227ea) at 283.15 and 293.15 K
Js. Lim et al., Phase equilibria of CFC alternative refrigerant mixtures. Binary systems of trifluoromethane (HFC-23)+1,1,1,2-tetrafluoroethane (HFC-134a) and trifluoromethane (HFC-23)+1,1,1,2,3,3,3-heptafluoropropane (HFC-227ea) at 283.15 and 293.15 K, J CHEM EN D, 46(6), 2001, pp. 1580-1583
Isothermal vapor-liquid equilibria for the binary mixtures of trifluorometh
ane (HFC-23) + 1,1,1,2-tetrafluoroethane (HFC-134a) and trifluoromethane 1,1,1,2,3,3,3-heptafluoropropane (HFC-227ea) were measured at 283.15 and 29
3.15 K. The experiments were carried out with a circulation-type equilibriu
m apparatus with measurement of the temperature, pressure, and compositions
of the liquid and vapor phases. The experimental data were correlated with
the Peng-Robinson equation of state using the Wong-Sandler mixing rules. R
esults calculated with this equation showed good agreement with the experim
ental data. Azeotropic behavior has not been found in either of these mixtu
res.