Electronic effects of donor and acceptor substituents on dipyrido(3,2-a : 2 ',3 '-c)phenazine (dppz)

Authors
Arancibia, A Concepcion, J Daire, N Leiva, G Leiva, AM Loeb, B Del Rio, R Diaz, R Francois, A Saldivia, M
Citation
A. Arancibia et al., Electronic effects of donor and acceptor substituents on dipyrido(3,2-a : 2 ',3 '-c)phenazine (dppz), J COORD CH, 54(3-4), 2001, pp. 323-336
Citations number
16
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
JOURNAL OF COORDINATION CHEMISTRY
ISSN journal
00958972 → ACNP
Volume
54
Issue
3-4
Year of publication
2001
Pages
323 - 336
Database
ISI
SICI code
0095-8972(2001)54:3-4<323:EEODAA>2.0.ZU;2-8
Abstract
The chelate ligands 11-R-dipyrido[3,2-a:2,3'-c]phenazine, dppz-R (R = NH2, CH3, H, COOH, NO2) and the Re(dppz-R)(CO)(3)Cl (R = NH2, COOH, NO2) complex es were synthesized and characterized by conventional techniques. The influ ence of the donor and acceptor properties of the R substituents on the liga nd properties were studied by spectroscopic techniques such as H-1-NMR and UV-Vis. Theoretical calculations were also achieved, mainly to interpret an d understand the experimental spectra.