Semiconductor copper(II) macrocyclic complexes. Synthesis, characterization and electrical properties of copper(II) complexes of the type [Cu(TAABL)](NO3) center dot nH(2)O with L = NH(CH2)(2)NH2, NH(CH2)(4)NH2, NH(CH2)(12)NH2, and the complex [Cu(TAAB(C14H9N2O2)(2))] center dot 4H(2)O

Authors
Ortiz-Rebollo, A Garcia-Montalvo, V Gomez-Lara, J Sanchez-Vergara, ME
Citation
A. Ortiz-rebollo et al., Semiconductor copper(II) macrocyclic complexes. Synthesis, characterization and electrical properties of copper(II) complexes of the type [Cu(TAABL)](NO3) center dot nH(2)O with L = NH(CH2)(2)NH2, NH(CH2)(4)NH2, NH(CH2)(12)NH2, and the complex [Cu(TAAB(C14H9N2O2)(2))] center dot 4H(2)O, J COORD CH, 54(3-4), 2001, pp. 441-453
Citations number
20
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
JOURNAL OF COORDINATION CHEMISTRY
ISSN journal
00958972 → ACNP
Volume
54
Issue
3-4
Year of publication
2001
Pages
441 - 453
Database
ISI
SICI code
0095-8972(2001)54:3-4<441:SCMCSC>2.0.ZU;2-D
Abstract
The complexes [Cu(TAABNH(CH2)(2)NH2)](NO3). 2H(2)O, (1) [Cu(TAABNH(CH2)(4)N H2)] (NO3). 4H(2)O, (2), [Cu(TAABNH(CH2)(12)NH2](NO3). 4H(2)O, (3) and [Cu( TAAB(C14H10 N2O2)(2)]. 4H(2)O, (4) have been synthesized and characterized by IR, mass spectroscopy, electronic spectroscopy, thermogravimetric analys is and elemental analysis. Electrical conductivity and activation energy ev aluation were obtained from study of the temperature dependence of the elec trical current (in tablet and thin film). Refraction and reflectance indice s, absorption coefficient and optical activation energy were established th rough ellipsometry and UV-Vis spectroscopy. The electrical conductivity val ues at room temperature were within the range of semiconducting molecular s olids (10(-6)-10(1)Omega (-1) cm(-1)).